Batman: The Animated Series - Season 1 Episode 17 -
Two-Face (1)
Mobster Rupert Thorne attempts to use Harvey Dent's secret split personality to blackmail him. But when Dent meets with Thorne at a chemical plant, "Big Bad Harv" takes over, and the resulting confrontation leads to an explosion that horribly scars half of Dent's face.
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