The Simpsons - Season 8 Episode 9 -
Season 8, Episode 9 - El Viaje Misterioso de Nuestro Jomer (The Mysterious Voyage of Our Homer)
At Springfield's annual chili cook-off, Homer eats a spicy concoction containing hallucinogenic peppers from Guatemala, and subsequently has a vision which makes him doubt Marge is his soul mate.
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